Tepic - a New High Temperature Structural Foam

The formulation, processing characteristics, microstructure and mechanical properties of a new structural foam, suitable for use at service temperatures up to 200°C, are reported. In each of these respects, the foam is compared to an existing material, called APO-BMI that is currently in use. When these two foams are directly compared, the new foam, called TEPIC, is found to be superior in its mechanical performance. TEPIC is formulated from a non-carcinogenic isocyanate, a di-functional epoxide, and glass rnicroballoons. Our approach was to combine chemistries known to form therrnaUy stable products. The principal polymerization products are an oxizolidinone produced by the reaction of the isocyanate with the epoxide and isocyanurate rings formed by the trimerization of the isocyanate. Processing has been examined and large-scale production is discussed in detail. Compared to APO-BMI processing, TEPIC processing is fwile and economical. The structure of the foam resembles a traditional rigid polyurethane foam rather than that of the APO-BMI. That is, the foam is comprised of a continuous resin phase rather thau weakly bonded glass microballoons. At a density of 0.42 g/cm3 or greater, maximum pore size in TEPIC was less than 2 ~ as required for the application.